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Syntheses and conversion of polyhedral compounds. 26. Synthesis of new heteropolyhedral compounds by heterocyclization of certain 3,7-disubstituted derivatives of 3,7-diaza-and 1,3,7-triazabicyclo-[3.3.1]nonanes

✍ Scribed by Ts. E. Agadzhanyan; G. L. Arutyunyan; R. A. Movsesyan


Publisher
Springer US
Year
1998
Tongue
English
Weight
313 KB
Volume
34
Category
Article
ISSN
0009-3122

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## Abstract The azabicyclic __endo__ compound 3 was synthesized by reaction of enamine 1 with 2‐benzoyl‐1,3‐dichloropropane (2). The thermodynamically more stable __exo__ isomer 4 was obtained by epimerization of 3 with sodium methoxide. The reduction of 3 and 4 was carried out with different reduc