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Syntheses and characterization of pentacoordinate organo-tin(IV) complexes II

โœ Scribed by Ji-Tao Wang; Yun-Wen Zhang; Yu-Ming Xu; Zhi-Wen Wang

Publisher
John Wiley and Sons
Year
1995
Tongue
English
Weight
293 KB
Volume
6
Category
Article
ISSN
1042-7163

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โœฆ Synopsis

Nine substituted benzoyl hydrazonyl, three semicarbazonyl, and four thiosemicarbazonyl tridentate ligands were synthesized. They were used to coordinate with Bu,SnCl, or (PhCH,),SnCl, to form 18 novel tin complexes that contained pentacoordinate organotin (IV) in a heterobicyclic ring. All these complexes were characterized by MS, NMR, and IR spectroscopy elemental analyses. 0 I995 John Wiley & Sons, Inc.

๐Ÿ“œ SIMILAR VOLUMES

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Syntheses and characterization of pentacoordinate organo-tin(IV) complexes
โœ Ji-Tao Wang; Yun-Wen Zhang; Yu-Ming Xu; Zhi-Wen Wang ๐Ÿ“‚ Article ๐Ÿ“… 1992 ๐Ÿ› John Wiley and Sons ๐ŸŒ English โš– 296 KB

Ten novel pentacoordinate organo-tin complexes were prepared and characterized. Single crystal structure determinations by X-ray diffraction and also chemical investigations were made.

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A mononuclear precursor complex, [(CH 3 ) 2 Sn(tpdtc)] and several of its heterobimetallic derivatives of the type, [(CH 3 ) 2 Sn(tpdtc)]MCl 2 have been synthesized by the simple addition reaction of transition metal chlorides, MCl 2 รnH 2 O where tpdtc = tetraethylenepentamine bis(dithiocarbamate)