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Syntheses and characterization of oxo-molybdenum(IV) complexes with thiolate ligands as model complexes of reduced molybdo-oxidases

✍ Scribed by Mitsuru Kondoh; Norikazu Ueyama; Akira Nakamura; Keiichi Fukuyama

Publisher
Elsevier Science
Year
1991
Tongue
English
Weight
78 KB
Volume
43
Category
Article
ISSN
0162-0134

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Redox Chemistry in the Reaction of Oxova
Redox Chemistry in the Reaction of Oxovanadium(V) with Thiolate-Containing Ligands: the Isolation and Characterization of Non-Oxo Vanadium(IV) Complexes Containing Disulfide and Thioether Groups
✍ Hua-Fen Hsu; Chia-Ling Su; Neeruganti O. Gopal; Chi-Chin Wu; Wei-Cheng Chu; Yi-F πŸ“‚ Article πŸ“… 2006 πŸ› John Wiley and Sons 🌐 English βš– 158 KB

## Abstract The reactions of V^V^O(O‐__i__Pr)~3~ with [PS3β€²]H~3~ and [PS3]H~3~ {[PS3β€²]H~3~ = P(C~6~H~3~‐5‐Me‐2‐SH)~3~, [PS3]H~3~ = P(C~6~H~4~‐2‐SH)~3~} led to the formation of [V^IV^(L)] [L = P2S4β€² (1a), P2S4 (1b)], where L was formed by the oxidative coupling of two PS3β€² or PS3 ligands by a disulf