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Synthesen auf dem Gebiet des 2,4,6-Trioxo-1,3,5-triazabicyclo[3,3,0]octans

✍ Scribed by Prof. Dr. G. Zinner; D. Böse

Publisher
John Wiley and Sons
Year
1970
Tongue
English
Weight
164 KB
Volume
303
Category
Article
ISSN
0365-6233

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✍ Skoda, Lutz ;Klingebiel, Uwe ;Meller, Anton 📂 Article 📅 1980 🏛 Wiley (John Wiley & Sons) 🌐 English ⚖ 328 KB

The reaction of mono-and dilithio-2,2,4,4,6,6-hexamethylcyclotrisilazane (1, 2) with aminofluorosilanes R -SiF,-NR'SiMe, (R = F, Me; R' = CMe,, SiMe,) leads to LiF elimination and format'ion of the cyclotrisilazanes 3 -5. The cyclodisilazane 6 is obtained by ring contraction in the reaction of compo