Synthese von Thieno-[2′,3′∶4,5]pyrimido[1,2—b][1,2]benzisothiazolderivaten
✍ Scribed by F. Sauter; W. Deinhammer
- Book ID
- 105000933
- Publisher
- Springer Vienna
- Year
- 1974
- Tongue
- English
- Weight
- 143 KB
- Volume
- 105
- Category
- Article
- ISSN
- 0026-9247
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## Abstract magnified image An efficient one‐pot access for the synthesis of the previously unreported tetracyclic fused pyrimido‐[4″,5″:4′,5′]thieno[3′,2′:4,5]thieno[3,2‐__d__]pyrimidine (**3**) and 1,2,3‐triazine[4″,5″:4′,5′]thieno‐[3′,2′:4,5]thieno‐[3,2‐__d__]‐1,2,3‐triazine (**5**) heteroaroma
**Syntheses of New Salts of Thieno[2′,3′;4,5]imidazo[1,2‐a]pyridines** Mesomeric 1‐[2‐amino‐1‐cyano‐2‐thio‐]ethene‐pyridinium ylides **1** are cyclizized to imidazo[1,2‐a]pyridinium ylides **2** in the presence of HgO. S‐alkylation of **2** leads to derivatives of 1‐R^1^‐2‐thio‐3‐cyano‐imidazo[1,2‐