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Synthese von metallorganischen Estern der Chromsäure (Ph3MO)2CrO2 (Ph = C6H5, M = Ge, Sn, Pb)

✍ Scribed by Karel Handliř; Jaroslav Holeček; Milan Nádvornik; Jiři Klikorka

Book ID
104610264
Publisher
Wiley (John Wiley & Sons)
Year
2010
Weight
311 KB
Volume
20
Category
Article
ISSN
0044-2402

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Addition des O'Donnell Reagenzes [Ph2C=NCHCO2Me]– an π-koordinierte, ungesättigte Kohlenwasserstoffe in [(C6H7)Fe(CO)3]+, [(C7H9)Fe(CO)3]+, [(C7H7)M(CO)3]+ (M = Cr, Mo) und [(C2H4)Re(CO)5]+. α-Aminosäuren mit metallorganischen Seitenketten
✍ Theodor Ederer; Karlheinz Sünkel; Wolfgang Beck 📂 Article 📅 1999 🏛 John Wiley and Sons 🌐 German ⚖ 126 KB 👁 1 views

The addition of [Ph 2 C=NCHCO 2 Me] ± to [(C 6 H 7 )Fe(CO) 3 ] + , [(C 7 H 9 )Fe(CO) 3 ] + , [(C 7 H 7 )M(CO) 3 ] + (M = Cr, Mo) and [(C 2 H 4 )Re(CO) 5 ] + gives derivatives of aamino acids with organometallic side chains. The structure of [(g 4 -C 6 H 7 )CH(N=CPh 2 )CO 2 Me]Fe(CO) 3 was determined