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Synthese und Kristallstruktur von [(PhCH2)2GaF(tBuNH2)]2 · 2 THF

✍ Scribed by Mike R. Kopp; Bernhard Neumüller

Publisher
John Wiley and Sons
Year
1999
Tongue
German
Weight
67 KB
Volume
625
Category
Article
ISSN
0372-7874

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✦ Synopsis

Synthesis and Crystal Structure of [(PhCH 2 ) 2 GaF( t BuNH 2 )] 2 ´2 THF Abstract. (PhCH 2 ) 2 GaF reacts with t BuNH 2 to the adduct [(PhCH 2 ) 2 GaF( t BuNH 2 )] (1). 1 was characterized by NMR, IR and MS techniques. 1 can be recrystallized from THF forming crystals of [1] 2 ´2 THF. According to an X-ray structure analysis [1] 2 ´2 THF consists of dimers of 1 formed by hydrogen bridges. The THF molecules are coordinated to [1] 2 by hydrogen bridges, too.

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