Synthese, Struktur und Reaktionen von α-Campholenepoxiden

✍ Scribed by Schulze, Klaus ;Habermann, Anne-Kathrin ;Uhlig, Holger ;Weber, Lutz ;Kempe, Rhett

• Publisher: John Wiley and Sons
• Year: 1993
• Tongue: English
• Weight: 521 KB
• Volume: 1993
• Category: Article
• ISSN: 0947-3440
• DOI: 10.1002/jlac.1993199301157

✦ Synopsis

Synthesis, Structure and Reactions of α‐Campholenic Epoxides

The epoxidation of α‐campholenic compounds 3, 4 is described, besides the rearrangement of the epoxides 5 and 6 into the hydroxy‐β‐campholenic system 7, 8, the reduction to the tertiary alcohols 11a, 12a, the alkylation reaction to 11b and 12b and the conversion of 7 into the diketone 10 are reported. The stereochemistry and the odour of the new compounds are also described.