Synthese et proprietes electrochimiques de sels conducteurs derives du tetramethyltetraselenofulvalene–II. perchlorate, tetrafluoroborate, hexafluorophosphate

✍ Scribed by Myriam Lamache; Soekirno Wuryanto; Frank Benhamou

• Publisher: Elsevier Science
• Year: 1985
• Tongue: English
• Weight: 463 KB
• Volume: 30
• Category: Article
• ISSN: 0013-4686
• DOI: 10.1016/0013-4686(85)80133-x

✦ Synopsis

RCmn6L'oxydation de TMTSF en prbsence de diffhrents anions (X-= ClOi , BF;, PF; ) a it6 6tudiie par plusieurs methodes Clectrocbimiques. Darts chaque cas un solide de composition TMTSF,X a it6 isole par Bectrolyse, et son comportement 6lectrochimique deduit de l'analyse des courbes intensit&potentiel obtenues avec une Clectrode a p&e de carbone.

Abstract-The oxidation of TMTSF in the presence of different anions (X-= ClO;, BF,, PF;) has been studied by several electrochemical methods. In each case the solid phase TMTSF,X has been isolated by electrolysis and its electrochemical behaviour deduced from the analysis of the current-voltage curves obtained with a carbon-paste electrode.