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Synthese enantiomerenreiner 1,7-Dioxaspiro[5.5]undecane, einer Pheromonkomponente der Olivenfliege (Dacus oleae)

โœ Scribed by Priv.-Doz. Dr. Hartmut Redlich; Priv.-Doz. Dr. Wittko Francke


Publisher
John Wiley and Sons
Year
1984
Tongue
English
Weight
253 KB
Volume
96
Category
Article
ISSN
0044-8249

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Synthesis of Enantiomerically Pure 1,7-D
โœ Priv.-Doz. Dr Hartmut Redlich; Priv.-Doz. Dr Wittko Francke ๐Ÿ“‚ Article ๐Ÿ“… 1984 ๐Ÿ› John Wiley and Sons ๐ŸŒ English โš– 262 KB ๐Ÿ‘ 1 views

On reduction with NaBH4 in methanol (or 2-propanol) or LiAlH4 in tetrahydrofuran (THF), the 2-acylindoles 1 are converted into the 2-( 1-hydroxyalky1)indole derivatives 2. The 2-(3-dimethylaminopropionyl)indoles l c and Id are obtained from the 2-acetylindoles laL3] and lbI4], respectively, by Manni