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Synthese, Charakterisierung und UV-VIS-spektroskopisches Verhalten von 4-benzhydrylamino-substituierten Azobenzolen

✍ Scribed by Prof. Dr. J. Epperlein; S. Mais; B. Blau


Publisher
John Wiley and Sons
Year
1992
Tongue
English
Weight
279 KB
Volume
334
Category
Article
ISSN
1615-4150

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UV/VIS-spektroskopischer Nachweis einer
✍ Emma Thorn-Csányi; Jörg Dehmel; Olaf Halle; Winfried Sciborski 📂 Article 📅 1994 🏛 John Wiley and Sons 🌐 English ⚖ 401 KB

## Abstract The kinetic analysis of the reaction between WOCl~4~ and trimethylaluminium (TMA) shows that TMA forms a 2 : 1 mol/mol‐complex with WOCl~4~ before it acts as an alkylating agent. The reaction steps can be observed separately because rate constants __k__~complex formation~ ≫ __k__~alkyla