Synergistic self-assembly of scaffolds and building blocks for directed synthesis of organic nanomaterials
β Scribed by Dergunov, Sergey A.; Richter, Andrew G.; Kim, Mariya D.; Pingali, Sai Venkatesh; Urban, Volker S.; Pinkhassik, Eugene
- Book ID
- 121231951
- Publisher
- Royal Society of Chemistry
- Year
- 2013
- Tongue
- English
- Weight
- 513 KB
- Volume
- 49
- Category
- Article
- ISSN
- 1359-7345
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To investigate the relationship between topological types and molecular building blocks (MBBs), we have designed and synthesized a series of three-dimensional (3D) interpenetrating metal-organic frameworks based on different polygons or polyhedra under hydrothermal conditions, namely [Cd(bpib) 0.5 (
The structure of 7 is characterized by two parallel Cp\* rings; the distance between the two Co atoms (2.253(1) A) is 0.08 A shorter than in [Cp:Co, (p-CO),].t'51 This finding