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Synergistic extraction of Ce(IV) and Th(IV) with mixtures of Cyanex 923 and organophosphorus acids in sulfuric acid media

✍ Scribed by Tong, Hui; Wang, Yanliang; Liao, Wuping; Li, Deqian


Book ID
122602268
Publisher
Elsevier Science
Year
2013
Tongue
English
Weight
830 KB
Volume
118
Category
Article
ISSN
1383-5866

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Kinetics of Ce(IV) oxidation of Ξ±-keto a
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The rates of oxidation of four a-keto acids, glyoxylic, pyruvic, phenylglyoxylic, and 2oxobutyric acids by Cerium(1V) in H2S04-HaHS04 and HzS04-HC104 solutions, have been studied spectrophotometrically. The rate data suggest that CeSO:' is the most reactive of the Cerium(1V)-sulfate complexes presen