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Synergistic effect of trimethylsilane for photoinduced electron transfer on 1,8-naphthalimides in polar solvent

✍ Scribed by Cho, Dae Won; Cho, Dae Won; Park, Hea Jung; Yoon, Ung Chan; Lee, Myoung Hee; Im, Chan

Book ID
120018207
Publisher
Elsevier Science
Year
2012
Tongue
English
Weight
633 KB
Volume
246
Category
Article
ISSN
1010-6030

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We conducted Monte Carlo simulations of polar solutions by explicitly treating the effect of electronic polarizability of solvent molecules. Based on these data, we calculated the energy-gap dependence of electron-transfer rates. It was found that a considerable asymmetry of the energy-gap dependenc