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Syndiotactic-Specific Polymerization of Propene with Nickel-Based Catalysts. 2. Regiochemistry and Stereochemistry of the Initiation Steps

✍ Scribed by Pellecchia, Claudio; Zambelli, Adolfo; Oliva, Leone; Pappalardo, Daniela


Book ID
120651216
Publisher
American Chemical Society
Year
1996
Tongue
English
Weight
161 KB
Volume
29
Category
Article
ISSN
0024-9297

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Polymerization of propene with the XTiCl
✍ Kazuo Soga; Yoshifumi Suzuki; Toshiya Uozumi; Eiichi Kaji πŸ“‚ Article πŸ“… 1997 πŸ› John Wiley and Sons 🌐 English βš– 544 KB

Several kinds of MgC12-supported half titanocene (XTiCl~; X = cyclopentadienyl, pentamethylcyclopentadienyl, indenyl, and heptamethylindenyl) catalysts were prepared and applied to propene polymerization using Al(i-Bu)~as cocatalyst. It was confirmed from the catalyst analysis that the ligand (X) is