syn- undanti-Octamethyl-tricyclooctadien
✍ Scribed by Criegee, Rudolf ;Schröder, Gerhard ;Maier, Günther ;Fischer, Hans-Gerhard
- Publisher
- Wiley (John Wiley & Sons)
- Year
- 1960
- Tongue
- English
- Weight
- 390 KB
- Volume
- 93
- Category
- Article
- ISSN
- 0009-2940
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The syn dimer of cyclobutadiene (tricyclo[4.2.0.0(2.5)]octa-3,7-diene, TOD) is subjected to ionization under different conditions and the resulting species are probed by optical and ESR spectroscopy. By means of quantum chemical modelling of the potential energy surfaces and the optical spectra, it
## Abstract Die Titelsubstanz gibt mit Ozon außer dem Diketo‐mooozonid **4** das Diozonid **2**. Beide werden zu demselben Ketotrioxan **6** hydriert. Die Photolyse des Diozonids liefert neben drei Derivaten des Monoozonids das Trioxan **9** als Cyclisierungsprodukt des __all‐cis__‐Trimethyl‐triace