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syn-Sesqui- and -Sesterbenzobicyclo[2.2.2]octene, Molecules with Stacked Benzene Rings

✍ Scribed by Prof. Wolfram Grimme; Dr. Heinz Theo Kämmerling; Dr. Johann Lex; Prof. Rolf Gleiter; Prof. Jürgen Heinze; Dipl.-Chem. Michael Dietrich

Publisher: John Wiley and Sons
Year: 1991
Tongue: English
Weight: 346 KB
Volume: 30
Category: Article
ISSN: 0044-8249
DOI: 10.1002/anie.199102051

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## Abstract X‐ray analysis of a crystalline product obtained by treatment of 5‐ethylthieno[2,3‐__b__]pyridine with excess acidified hypochlorite establishes its stereochemistry as __trans__‐2,3‐dichloro‐5‐ethyl‐2,3‐dihydrothieno‐[2,3‐__b__]pyridine __syn__‐1‐oxide (5), wherein the pyridine ring is