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syn-Selective and Enantioselective Direct Cross-Aldol Reactions between Aldehydes Catalyzed by an Axially Chiral Amino Sulfonamide

✍ Scribed by Taichi Kano; Yukako Yamaguchi; Youhei Tanaka; Keiji Maruoka

Publisher
John Wiley and Sons
Year
2007
Tongue
English
Weight
96 KB
Volume
46
Category
Article
ISSN
0044-8249

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A Designer Axially Chiral Amino Sulfonam
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## Abstract **Amino sulfonamide catalyst**: A distal proton of the axially chiral amino sulfonamide (__S__)‐**1** realized the opposite diastereoselectivity in Mannich and cross‐aldol reactions compared with that observed in proline‐catalyzed reactions. The reactions catalyzed by (__S__)‐**1** proc

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## Abstract ChemInform is a weekly Abstracting Service, delivering concise information at a glance that was extracted from about 200 leading journals. To access a ChemInform Abstract of an article which was published elsewhere, please select a β€œFull Text” option. The original article is trackable v