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Syn selective aldol reactions of titanium and zirconium dienolates.

✍ Scribed by James S. Panek; Oleh A. Bula

Book ID
104217454
Publisher
Elsevier Science
Year
1988
Tongue
French
Weight
216 KB
Volume
29
Category
Article
ISSN
0040-4039

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✦ Synopsis

The low temperature transmetallation of the lithium dienolate of 2-cyclohexene-l-one or P-cyclopentene-1 -one with chlorotitanium triisopropoxide or bis(n5-cyclopentadienyl)dichlorozirconium gives the Z,E-titanium or zirconium dienolate. These transition metal dienolates participate in aldol reactions with achiral aldehydes resulting in the direct formation of a syn B-hydroxy enone system.

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## Abstract ChemInform is a weekly Abstracting Service, delivering concise information at a glance that was extracted from about 100 leading journals. To access a ChemInform Abstract of an article which was published elsewhere, please select a β€œFull Text” option. The original article is trackable v