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“Syn-Effect” in the Isomerization of (E)-α-Fluorovinylic Sulfones to the Corresponding Allylic Sulfones under Basic Conditions.

✍ Scribed by Tetsuya Nakamura; Samar Kumar Guha; Yoshihiro Ohta; Daisuke Abe; Yutaka Ukaji; Katsuhiko Inomata


Publisher
John Wiley and Sons
Year
2003
Weight
146 KB
Volume
34
Category
Article
ISSN
0931-7597

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✦ Synopsis


Abstract

For Abstract see ChemInform Abstract in Full Text.


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ChemInform Abstract: “syn-Effect” in the
✍ A. SHIBAYAMA; T. NAKAMURA; T. ASADA; T. SHINTANI; Y. UKAJI; H. KINOSHITA; K. INO 📂 Article 📅 2010 🏛 John Wiley and Sons ⚖ 35 KB 👁 1 views

syn-Effect" in the Desulfonylation Reaction of α,α-Dialkylated (E)-Allylic Sulfones. -Desulfonation of the title compounds, e.g. (I) and (IV), with a base furnishes preferentially the sterically unfavorable (Z)alkadienes. The relative degree of the "syn-effect", defined as effect stabilizing the sy