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(+)-syn-Benzotriborneol an enantiopure C3-symmetric receptor for water

✍ Scribed by Fabris, Fabrizio; De Lucchi, Ottorino; Nardini, Ilaria; Crisma, Marco; Mazzanti, Andrea; Mason, Sax A.; Lemée-Cailleau, Marie-Hélène; Scaramuzzo, Francesca A.; Zonta, Cristiano


Book ID
118176527
Publisher
Royal Society of Chemistry
Year
2012
Tongue
English
Weight
626 KB
Volume
10
Category
Article
ISSN
1477-0520

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(+)-syn-Benzotriborneol: the first funct
✍ Fabrizio Fabris; Luca Bellotto; Ottorino De Lucchi 📂 Article 📅 2003 🏛 Elsevier Science 🌐 French ⚖ 202 KB

Copper(I) thiophencarboxylate readily and effectively cyclotrimerises protected 5-bromo-6-trimethylstannylborn-5-en-2ols, leading to oxygen-functionalised benzocyclotrimers. The remarkably high syn to anti ratio is driven by relative displacement of the halide and metal on the alkene moiety and depe