Symmetry of hydrogenated C60
β Scribed by Yihan Shao; Yuansheng Jiang
- Publisher
- Elsevier Science
- Year
- 1995
- Tongue
- English
- Weight
- 307 KB
- Volume
- 242
- Category
- Article
- ISSN
- 0009-2614
No coin nor oath required. For personal study only.
β¦ Synopsis
A graphical concept, which we call 'spiral-like' paths, is applied to the discussion of the point group symmetries of hydrogenated C6o. It is established that the symmetry of a C6oHm isomer satisfies: (i) it is a subgroup of the I h group of the parent molecule; (ii) for a subgroup with one or more symmetry planes, its order is a factor of 2m; (iii) for a subgroup without symmetry planes, its order is a factor of m. All the possible symmetries of C6oHm are readily tabulated. 28 C1, C2,
π SIMILAR VOLUMES
Contrary to a recent suggestion that externally fluorinated C&Fe0 may posses I rather than 1s symmetry, we report theoretical ab initio evidence favoring an Ih equilibrium structure. However, as with C60H60, we find that the lowest minimum structure contains fluorine atoms inside the Cso cage. ## T