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Symmetry-Adapted Algebraic Description of Stretching and Bending Vibrations of Ozone

✍ Scribed by F. Pérez-Bernal; J.M. Arias; A. Frank; R. Lemus; R. Bijker

Publisher
Elsevier Science
Year
1997
Tongue
English
Weight
403 KB
Volume
184
Category
Article
ISSN
0022-2852

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✦ Synopsis

The vibrational excitations of ozone, including both bending and stretching vibrations, are studied in the framework of a symmetry-adapted algebraic approach. This method is based on the isomorphism between the U( 2) algebra and the one-dimensional Morse oscillator, and the introduction of point group symmetry techniques. The use of symmetryadapted interactions, which in the harmonic limit have a clear physical interpretation, makes it possible to systematically include higher-order terms and anharmonicities. A least-squares fit to all published experimental levels (up to 10 quanta) of 16 O 3 and 18 O 3 yields rms deviations of 2.5 and 1.0 cm 01 , respectively.

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