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Switching the mechanism of spin-exchange coupling in a (.mu.-oxo)bis(.mu.-acetato)chromium(III)vanadium(III) complex by protonation of the oxo bridge

โœ Scribed by Hotzelmann, Rainer; Wieghardt, Karl


Book ID
127128486
Publisher
American Chemical Society
Year
1993
Tongue
English
Weight
312 KB
Volume
32
Category
Article
ISSN
0020-1669

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Ab initio calculation of the magnetic ex
โœ Ch. Kolczewski; K. Fink; V. Staemmler ๐Ÿ“‚ Article ๐Ÿ“… 2000 ๐Ÿ› John Wiley and Sons ๐ŸŒ English โš– 328 KB ๐Ÿ‘ 2 views

Quantum chemical ab initio calculations have been performed for the magnetic exchange coupling in three linear oxo-bridged heterobinuclear transition-metal ลฝ . ลฝ . complexes of the form L M III -O-M III L with M , M s Ti, V, Cr. In order to 5 1 2 5 1 2 simplify the calculations, the terminal ligands