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Switching the Mechanism of Catalyst Activation by Ionic Liquids

✍ Scribed by Daguenet, Corinne; Dyson, Paul J.

Book ID: 127112861
Publisher: American Chemical Society
Year: 2006
Tongue: English
Weight: 109 KB
Volume: 25
Category: Article
ISSN: 0276-7333
DOI: 10.1021/om060728+

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## Abstract Michael additions of malonodinitrile as well as several other reagents to chalcone have been found to proceed well in pure ionic liquids, without the addition of any catalyst. The catalytic effect of the residual acidity caused by hydrolysis of ionic liquids anions was excluded because