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Switching between charge- and proton-transfer emission in the excited state of a substituted 3-hydroxyflavone

✍ Scribed by Stuart M. Ormson; Robert G. Brown; Friedrich Vollmer; Wolfgang Rettig


Publisher
Elsevier Science
Year
1994
Tongue
English
Weight
642 KB
Volume
81
Category
Article
ISSN
1010-6030

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A singk exponential risetime is observed for the tautomcr fluoresccncc of 3-hydroxyflavom in the absence of hydrogcnbonding impuriticsin the temperature range of 298-77 K. The observed risetime in hydrocarbon solvents is Its than 8 ps at 298 K. while at 77 K it is 37 2 6 ps. The disucpnncy with othe