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Switch of Selectivity in the Synthesis of α-Methylene-γ-Lactones: Palladium-Catalyzed Intermolecular Carboesterification of Alkenes with Alkynes

✍ Scribed by Liangbin Huang; Qian Wang; Xiaohang Liu; Prof. Dr. Huanfeng Jiang


Book ID
111678325
Publisher
John Wiley and Sons
Year
2012
Tongue
English
Weight
556 KB
Volume
51
Category
Article
ISSN
0044-8249

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## Abstract The methodology in this article is a palladium(II)/copper(II)‐ or palladium(II)‐catalyzed intermolecular cyclization of acrylic acid with alkenes to produce α‐methylene‐γ‐butyrolactone derivatives using molecular oxygen as an environmentally benign oxidant. In this system, the carboxyla