Swern oxidation of diaziridines to diazirines
โ Scribed by Richardson, Stewart K.; Ife, Robert J.
- Book ID
- 121267407
- Publisher
- Royal Society of Chemistry
- Year
- 1989
- Weight
- 175 KB
- Volume
- 6
- Category
- Article
- ISSN
- 1472-7781
No coin nor oath required. For personal study only.
๐ SIMILAR VOLUMES
A variety of alcohols have been oxidized under mild conditions by the DMSO-Ph 3 PโขX 2 complexes. The reaction does not produce any Pummerer product. A mechanism for the reaction is proposed.
The Swem oxidation of various indolic substrates is described, and a range of products resulting from overall oxidation at the 2-position were observed. In particular, depending on the substrate and reaction conditions, it was possible to achieve direct oxidation to cc,/5-unsaturated systems at the
A new approach towards the synthesis of glycosides based upon a (formal) insertion of glycosylidene carbenes into 0-H bonds is presented. The synthesis and characterization of the glycosylidene-derived diazirines 25-28, precursors of glycosylidene carbenes, are described. The diazirines were prepare