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Suzuki-Miyaura Coupling of Aryl Sulfonates with Arylboronic Acids Using a Morpholine-Pd(OAc) 2 Catalyst System

✍ Scribed by Abe, Taichi; Mino, Takashi; Watanabe, Kohei; Yagishita, Fumitoshi; Sakamoto, Masami


Book ID
124089183
Publisher
John Wiley and Sons
Year
2014
Tongue
English
Weight
549 KB
Volume
2014
Category
Article
ISSN
1434-193X

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Pd/P(i-BuNCH2CH2)3N: an efficient cataly
✍ Sameer Urgaonkar; M. Nagarajan; J.G. Verkade πŸ“‚ Article πŸ“… 2002 πŸ› Elsevier Science 🌐 French βš– 123 KB

Pd(OAc) 2 in combination with the commercially available ligand P(i-BuNCH 2 CH 2 ) 3 N catalyzes the Suzuki cross-coupling reaction of a wide variety of aryl bromides and chlorides with arylboronic acids, affording the desired biaryls in excellent yields. It has also been shown that P(NMe 2 ) 3 can