Fossil fuel reserves are diminishing rapidly across the world, intensifying the stress on existing reserves day-by-day due to increased demand. Not only that, fossil fuels, presently contributing to 80% of world primary energy, are inflicting enormous impacts on environment. Climatic changes driven by human activities, in particular the production of greenhouse gas emissions, directly impact the environment. Energy sector has a key role in this regard since energy during its production, distribution and consumption is responsible for producing environmentally harmful substances. A secure and accessible supply of energy is thus very crucial for the sustainability of modern societies. There is an urgent need for a quicker switch over of energy systems from conventional to renewables that are sustainable and can meet the present and projected world energy demand. Solar power is one of the most promising renewables. It is reliable and less vulnerable to changes in seasonal weather patterns. Hydrogen, in the capacity of energy vector, is expected to be the optimum solution for intermittency and storage of energy produced by renewables. Thus, coupled with hydrogen as an energy carrier, solar energy has a large potential to become the fuel of the future. The present study is aimed to explore such potential for India in 2025. India is expected to have a high growth rate in energy demand over the coming years due to its huge population and rapid economic development. By the year 2020, the country's demand for commercial energy is expected to increase by a factor of 2.5. Presently, more than 90% of the energy demand is met by fossil fuels, in spite of the fact that India has limited fossil fuel resources as compared to global reserves. By the year 2020, India, presently the world's sixth largest energy consumer, is expected to meet 75% of its oil and gas needs by imports. Being an energy deficient country, it has not been able to keep up with demand, leading to power shortages and supply interruptions. The growing gap between the demand and supply of energy, and environmental externalities associated with fossil fuel require immediate and substantial Renewable and Sustainable Energy Reviews 9 (2005)