𝔖 Bobbio Scriptorium
✦   LIBER   ✦

Surprising Formation of Chlorinated Butenolides from Dialkyl Acetylenedicarboxylates and Hexachloro­acetone in the Presence of Triphenyl Phosphite

✍ Scribed by Issa Yavari; Maryam Sabbaghan; Zinatossadat Hossaini; Majid Ghazanfarpour-Darjani

Publisher
John Wiley and Sons
Year
2008
Tongue
German
Weight
145 KB
Volume
91
Category
Article
ISSN
0018-019X

No coin nor oath required. For personal study only.

✦ Synopsis

Abstract

Triphenyl phosphite reacts smoothly with dialkyl acetylenedicarboxylates and hexachloroacetone to produce alkyl 2‐(dichloromethylene)‐2,5‐dihydro‐5‐oxo‐4‐(trichloromethyl)furan‐3‐carboxylates in good yields.

📜 SIMILAR VOLUMES

Synthesis of aromatic amine phosphonato
Synthesis of aromatic amine phosphonato ester derivatives from the stereoselective reaction between triphenyl phosphite and dimethyl acetylenedicarboxylate in the presence of derivatives of aromatic amines
✍ Malek Taher Maghsoodlou; Reza Heydari; Nourallah Hazeri; Sayyed Mostafa Habibi-K 📂 Article 📅 2009 🏛 John Wiley and Sons 🌐 English ⚖ 200 KB 👁 1 views

## Abstract Aromatic amine phosphonato esters **4a–d** were obtained in excellent yields from the 1:1:1 addition reaction between triphenyl phosphite and dimethyl acetylenedicarboxylate in the presence of NH‐aromatic amines such as 2‐aminobenzophenone, 2‐aminoacetophenon, methyl‐2‐aminobenzoate, an