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Surfaces—II: Kinematics of diffusion in a heterogeneous surface

✍ Scribed by John C. Slattery


Publisher
Elsevier Science
Year
1964
Tongue
English
Weight
224 KB
Volume
19
Category
Article
ISSN
0009-2509

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✦ Synopsis


In deriving the differential mass (momentum, moment-of-momentum,.

. .) balance for a moving surface, it is convenient to follow an arbitrary material volume through a deformation and to require that mass (momentum, moment-of-momentum, . . .) be balanced at every instant of time.

But there is a conceptual difficulty in following a volume composed of material particles or in taking a material derivative (an intrinsic derivative with respect to time along the path of a material particle) if mass transfer is taking place simultaneously. In order that definite meaning be given to these operations, a particle of mixture in a moving surface and the material derivative following a particle of mixture in a moving surface are defined for the case of simultaneous diffusion and deformation.


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✍ A.P. Gonzalez; V.D. Pereyra; J.L. Riccardo; G. Zgrablich 📂 Article 📅 1995 🏛 Elsevier Science 🌐 English ⚖ 326 KB

The kinetics of the A + A ~ 0 reaction on a correlated heterogeneous surface is studied. As a novel result it is found that the temporal behaviour of the density of A particles depends on the energetic topography of the surface when A particles are initially located preferently on the more energetic