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Surface vs. bulk reactivity in a solid-state methyl transfer

✍ Scribed by F.M. Menger; H.B. Kaiserman; L.J. Scotchie


Book ID
104232688
Publisher
Elsevier Science
Year
1984
Tongue
French
Weight
111 KB
Volume
25
Category
Article
ISSN
0040-4039

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## Abstract The rearrangement of methyl 2‐(methylthio)benzenesulfonate (1) to the zwitterionic 2‐(dimethyl‐sulfonium)benzenesulfonate (2) is known to proceed in solution by intermolecular Me transfers. The same rearrangement has been observed to occur in crystalline 1, but the crystal structure sho