Surface studies of ultra-high molecular weight polyethylene irradiated with high-energy pulsed electron beams in air

✍ Scribed by Oleg N. Tretinnikov; Shin-Ichi Fujita; Sakae Ogata; Yoshito Ikada

• Publisher: John Wiley and Sons
• Year: 1999
• Tongue: English
• Weight: 230 KB
• Volume: 37
• Category: Article
• ISSN: 0887-6266
• DOI: 10.1002/(sici)1099-0488(19990701)37:13<1503::aid-polb16>3.0.co;2-x

✦ Synopsis

Ultra-high molecular weight polyethylene (UHMWPE) was irradiated in air with high-energy (9 MeV), pulsed electron beams to doses ranging from 2.5 to 100 Mrad and subsequently heat treated at 120°C for a time period of 120 min. Surface characterization of the target side of irradiated UHMWPE samples was carried out both before and after the heat treatment by means of attenuated total reflection Fourier-transform infrared (FTIR/ATR) spectroscopy and microhardness measurement. The obtained results provided further evidence supporting our earlier observation (Tretinnikov, O. N.; Ogata, S.; Ikada, Y. Polymer 1998, 39, 6115) that thermal decomposition of hydroperoxides formed upon irradiation of UHMWPE with highenergy, pulsed electron beams in air leads to surface crosslinking, and the subsequent surface hardening of the irradiated polymer. Importantly, we found that this phenomenon has the highest contribution to the surface hardness enhancement of the polymer when the radiation dose is in the range of 10 -30 Mrad. In addition, we found that this irradiation and subsequent heat treatment of UHMWPE in air does not lead to formation of carbonyl-containing products unless the radiation dose exceeds 20 Mrad.