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Surface Structures in Thin Polymer Layers Caused by Coupling of Diffusion-Controlled Marangoni Instability and Local Horizontal Temperature Gradient

✍ Scribed by Lothar Weh


Publisher
John Wiley and Sons
Year
2005
Tongue
English
Weight
512 KB
Volume
290
Category
Article
ISSN
1438-7492

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✦ Synopsis


Abstract

Summary: Surface tension‐driven Marangoni convection causes the formation of regular surface structures in drying polymer layers. The shape of the surface structures formed during solvent evaporation depends on layer and interfacial dynamic parameters as well as external factors. The influence of a horizontal radial temperature gradient produced by a point heat source below the polymer layer on the diffusion‐controlled Marangoni instability has been studied. In the region of the lateral temperature gradient, radial surface flow coupled with the interfacial instability leads to stripe, ladder, chevron and/or labyrinthine surface structures.

Stepped ladder structures in a poly(vinyl butyral) layer produced by interfacial instability and heating with an ultrasonic sonotrode below the layer substrate.

magnified imageStepped ladder structures in a poly(vinyl butyral) layer produced by interfacial instability and heating with an ultrasonic sonotrode below the layer substrate.