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Surface Raman spectroscopy without enhancement: pyridine adsorbed on Ni(111) and Ni(100)

โœ Scribed by D. Harradine; Alan Campion


Publisher
Elsevier Science
Year
1987
Tongue
English
Weight
462 KB
Volume
135
Category
Article
ISSN
0009-2614

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โœฆ Synopsis


We report the Raman spectra of pyridine chemisorbed on Ni( 111) and Ni( 100) surfaces under ultrahigh vacuum. At coverages of 0.5 monolayer, the Raman spectrum is fully developed on the Ni( 100) surface while there is no observable spectrum on Ni( 111). The spectra at saturation coverages are nearly identical. These observations are interpreted as evidence for a higher coverage required for a compressional phase transition on Ni(l 1 1 ), which significantly enhances the Raman intensity.


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