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Surface photochemistry: The photo-chlorination of aromatic hydrocarbons with ferric chloride on alumina

✍ Scribed by Masato Hasebe; Catherine Lazare; Paul de Mayo; Alan C. Weedon

Publisher: Elsevier Science
Year: 1981
Tongue: French
Weight: 204 KB
Volume: 22
Category: Article
ISSN: 0040-4039
DOI: 10.1016/s0040-4039(01)92444-x

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✦ Synopsis

Irradiation of a number of aromatic hydrocarbons adsorbed on alumina in the presence of ferric chloride leads to monochlorination. A number of thermally-induced halogenations of aromatic hydrocarbons in the presence of cupric1 or ferric' halides have been reported. These reactions were carried out by heating the reagents in a high-boiling solvent (e.g. nitrobenzene, chlorobenzene) and were rather

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