Surface Orientation of Pyrazine Adsorbed on Silver from the Surface-Enhanced Raman Scattering Recorded at Different Electrode Potentials
✍ Scribed by Soto, J.; Fernández, D. J.; Centeno, S. P.; López Tocón, I.; Otero, J. C.
- Book ID
- 125989959
- Publisher
- American Chemical Society
- Year
- 2002
- Tongue
- English
- Weight
- 65 KB
- Volume
- 18
- Category
- Article
- ISSN
- 0743-7463
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📜 SIMILAR VOLUMES
SERS from crystal rlolct (CV) on a Ag clectrodc was mvcslqakd under prcrrsonsncc and resonance condltlons. The ckcll~llon prolilc of the chcmaorbcd spccics is Me that of chsrolvcd mokculcs but mtcnsltirs ZUIL' =I000 tnncs luger. The Raman enhancement IS = IO8 and ckhlblts 3 spcc~lic potcntlal dcpcnd
Enhanced Raman scattering has been observed from the hexacyanoferrate (II) and (III) ions adsorbed on Ag electrode surfaces. In the former case, five vibrational modes in the low-frequency range (214, 373,423,494 and 560 cm-') and four in the nitrilc-stretching region (2026,2067,2082 and 2122 cm-')