✦ LIBER ✦
Surface Organometallic Chemistry on Oxides: The First Well-Defined Selenium(IV) Derivative Grafted onto Silica
✍ Scribed by Hélène Provendier; Catherine C. Santini; Jean-Marie Basset; Laurent Carmona
- Book ID
- 102168277
- Publisher
- John Wiley and Sons
- Year
- 2003
- Tongue
- English
- Weight
- 143 KB
- Volume
- 2003
- Category
- Article
- ISSN
- 1434-1948
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✦ Synopsis
Abstract
Treatment of (EtO)~2~SeO with Aerosil silica dehydroxylated at 500 °C results in the formation of a unique surface derivative [≡SiO−Se(O)OEt] (1), which has been fully characterized by elemental analysis, IR, labelling reaction and solid‐state NMR spectroscopy. This is the first example of a silica‐supported selenium(IV) derivative. (© Wiley‐VCH Verlag GmbH & Co. KGaA, 69451 Weinheim, Germany, 2003)