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Surface organometallic chemistry of tin: reactivity of tetraalkyltin complexes and tributyltin hydride toward silica

✍ Scribed by Nedez, C.; Theolier, A.; Lefebvre, F.; Choplin, A.; Basset, J. M.; Joly, J. F.


Book ID
120494757
Publisher
American Chemical Society
Year
1993
Tongue
English
Weight
912 KB
Volume
115
Category
Article
ISSN
0002-7863

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Surface organometallic chemistry on meta
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The stoichiometry and the kinetics of the hydrogenolysis of tetra n-butyl tin on silica and alumina supported rhodium catalysts has been determined at 298 K in n-heptane. Various Rh/Si02 and Rh/A1203 catalysts have been prepared by exchange from [ RhCl( NH3)5] (OH), and by impregnation from F&Cl3 re