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Surface-initiated atom transfer radical polymerization of polyhedral oligomeric silsesquioxane (POSS) methacrylate from flat silicon wafer

✍ Scribed by Renxu Chen; Wei Feng; Shiping Zhu; Gianluigi Botton; Beng Ong; Yiliang Wu


Book ID
108248331
Publisher
Elsevier Science
Year
2006
Tongue
English
Weight
204 KB
Volume
47
Category
Article
ISSN
0032-3861

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## Abstract Hydrophilic polymer brushes grown via surface‐initiated ATRP from silicon oxide surfaces are susceptible to detachment via hydrolytic cleavage of the anchoring siloxane bond. This paper investigates the influence of the structure of the ATRP initiator on the stability of these brushes a