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Surface Grafting of Poly( l -glutamates). 2. Helix Orientation

โœ Scribed by Wieringa, R. H.; Siesling, E. A.; Werkman, P. J.; Angerman, H. J.; Vorenkamp, E. J.; Schouten, A. J.

Book ID
127250019
Publisher
American Chemical Society
Year
2001
Tongue
English
Weight
100 KB
Volume
17
Category
Article
ISSN
0743-7463

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Helix sense of poly-ฮณ-p-chlorobenzyl L-g
Helix sense of poly-ฮณ-p-chlorobenzyl L-glutamate
โœ Eric H. Erenrich; Rudolph H. Andreatta; Harold A. Scheraga ๐Ÿ“‚ Article ๐Ÿ“… 1969 ๐Ÿ› Wiley (John Wiley & Sons) ๐ŸŒ English โš– 188 KB

Poly(7-p-chlorobenzyl cglutamate), for which theoretical calculations have shown only a small difference in energy between the left-and right-handed a-helices, has been synthesized and its screw sense determined by ORD in various solvents. In all solvents studied, a right-handed a-helix has been obs