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Surface-Functionalized, Ring-Opening Metathesis Polymerization-Derived Monoliths for Anion-Exchange Chromatography

✍ Scribed by Karoline Eder; Christian G. Huber; Michael R. Buchmeiser

Book ID: 102496424
Publisher: John Wiley and Sons
Year: 2007
Tongue: English
Weight: 156 KB
Volume: 28
Category: Article
ISSN: 1022-1336
DOI: 10.1002/marc.200700467

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✦ Synopsis

Abstract

Ring‐opening metathesis polymerization (ROMP) was used for the synthesis of monolithic capillary columns with inner diameters of 200 µm. The resulting polymeric monoliths were characterized by inverse size‐exclusion chromatography (ISEC). Surface functionalization was carried out in situ using 2‐(N,N‐dimethylaminoethyl)norborn‐5‐ene‐2‐ylcarboxylic amide (1). The resulting functionalized monoliths were successfully used in anion‐exchange chromatography of oligodeoxynucleotides.

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