Surface enrichment in blends of miscible polymers
โ Scribed by Bernhard Guckenbiehl; Manfred Stamm; Tasso Springer
- Publisher
- Elsevier Science
- Year
- 1994
- Tongue
- English
- Weight
- 480 KB
- Volume
- 86
- Category
- Article
- ISSN
- 0927-7757
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โฆ Synopsis
The surface in binary blends of the partially miscible polymers deuterated polystyrene and poly(styreneco-4.bromostyrene) with 6% brominated monomer units and various bulk compositions was studied by neutron reflection. Both the time-dependent and equilibrium properties of the blend are discussed. It is found that density profiles predicted by mean field theory are suitable to fit the experimental data. A depletion layer is established in the near surface region before equilibrium is reached. Properties like the FloryyHuggins interaction parameter x and the diffusion coefficient D are calculated and compared with recent experimental results.
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