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Surface-enhanced Raman scattering from tetracyanoethylene deposited on thin Ag films and charge transfer effects

โœ Scribed by Y.C. Chou; N.T. Liang


Publisher
Elsevier Science
Year
1984
Tongue
English
Weight
382 KB
Volume
106
Category
Article
ISSN
0009-2614

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โœฆ Synopsis


Raman spectra of tetwcyanocthylene (TCNE) deposited on rough Ag tllms were studied with an AI+ Iaer. TCNE was found to form a charge transfer complex with silver. The effects of charge transfer on the surkecnhanced Raman scattering are discussed.


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Effects of underpotentially deposited TI
โœ T. Watanabe; N. Yanagihara; K. Honda; B. Pettinger; L. Moerl ๐Ÿ“‚ Article ๐Ÿ“… 1983 ๐Ÿ› Elsevier Science ๐ŸŒ English โš– 642 KB

## SERS from pyridine on an Ag clccrrode is almost complcrely quenched by underpotential deposition of Tl 10 a surface covemgc of J 3%. Removal of Tl by anodic stripping does not restore the original SERS intensity. These results susest that only a small fraction of adsorbed pyridine molecules is