Surface-doping of Cr2O3 particles by the 119Sn Mössbauer probe: Influence of the gaseous environment on the dopant distribution
✍ Scribed by I.S. Bezverkhy; M.I. Afanasov; M. Danot; P.B. Fabritchnyi
- Book ID
- 114065451
- Publisher
- Elsevier Science
- Year
- 2000
- Tongue
- English
- Weight
- 86 KB
- Volume
- 35
- Category
- Article
- ISSN
- 0025-5408
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📜 SIMILAR VOLUMES
Room-temperature exposure of tin-doped Cr 2 O 3 surfaces to HF induces in the 119 Sn MoK ssbauer spectra changes that depend on the valence state of the tin probe and show di4erences between the Sn(II)-and Sn(IV)-containing Cr 2 O 3 crystallite surfaces. In the Sn(II)-doped samples (Sn(II)/Cr 2 O 3
Appearance of a particular tin dopant ion distribution with respect to the surface of Cr 2 O 3 substrate after H 2 S adsorption and subsequent exposure of the sample to air at room temperature has been revealed using 119 Sn probe Mo¨ssbauer spectroscopy. The results obtained show that drastic change