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Surface Coordination of Nitric Oxide to a Self-Assembled Monolayer of a Triruthenium Cluster: An in Situ Infrared Spectroscopic Study

✍ Scribed by Zhou, Wei; Zhang, Yi; Abe, Masaaki; Uosaki, Kohei; Osawa, Masatoshi; Sasaki, Yoichi; Ye, Shen

Book ID
126004777
Publisher
American Chemical Society
Year
2008
Tongue
English
Weight
283 KB
Volume
24
Category
Article
ISSN
0743-7463

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Oxidation States and CO Ligand Exchange
Oxidation States and CO Ligand Exchange Kinetics in a Self-Assembled Monolayer of a Triruthenium Cluster Studied by In Situ Infrared Spectroscopy
✍ Wei Zhou; Shen Ye; Masaaki Abe; Takuma Nishida; Kohei Uosaki; Masatoshi Osawa; Y 📂 Article 📅 2005 🏛 John Wiley and Sons 🌐 English ⚖ 321 KB 👁 1 views

## Abstract Oxidation states and CO ligand exchange kinetics in a self‐assembled monolayer (SAM) of an oxo‐centered triruthenium cluster [Ru~3~(μ~3~‐O)(μ‐CH~3~COO)~6~(CO)(L^1^)(L^2^)] (L^1^ = [(NC~5~H~4~)CH~2~NHC(O)(CH~2~)~10~S‐]~2~, L^2^ = 4‐methylpyridine) have been extensively investigated on th