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Supramolecular Templating of the Double-Cubane [{Cu3(HpztBu)6(μ3-Cl)(μ3-OH)3}2Cu]Cl6 (HpztBu=5-tert-Butylpyrazole)

✍ Scribed by Xiaoming Liu; Judith A. McAllister; Marcelo P. de Miranda; Benjamin J. Whitaker; Colin A. Kilner; Mark Thornton-Pett; Malcolm A. Halcrow


Publisher
John Wiley and Sons
Year
2002
Tongue
English
Weight
124 KB
Volume
41
Category
Article
ISSN
0044-8249

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Supramolecular Templating of the Double-
✍ Xiaoming Liu; Judith A. McAllister; Marcelo P. de Miranda; Benjamin J. Whitaker; 📂 Article 📅 2002 🏛 John Wiley and Sons 🌐 English ⚖ 124 KB

While the [M 4 (m 3 -X) 4 ] 4 (M transition ion, X anion or dianion) cubane structure is a common motif in transition metal chemistry and biochemistry, only a few examples of vertex-sharing double-cubane compounds are known. [1±8] We note in particular 1 (bipym 2,2'-bipyrimidine), which is the only