✦ LIBER ✦

Supramolecular Self-Assemblies of Two-Directional Cascade Molecules: Automorphogenesis

✍ Scribed by Prof. George R. Newkome; Dr. Charles N. Moorefield; Dr. Gregory R. Baker; Dr. Rajani K. Behera; Gregory H. Escamillia; Dr. Mary J. Saunders

Publisher: John Wiley and Sons
Year: 1992
Tongue: English
Weight: 441 KB
Volume: 31
Category: Article
ISSN: 0044-8249
DOI: 10.1002/anie.199209171

No coin nor oath required. For personal study only.

✦ Synopsis

I t is conceivable that an appropriate biological nucleophile could undergo a 1,6 Michael addition to the quinone via the exocyclic defin. Subsequent expulsion of the methoxyl group at C9a would provide the corresponding C10-substituted mitosene and provide net activation of mitomycin K without initial activation.

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