Supramolecular interactions of vanadate species: vanadium(V) complexes with N-salicylidenehydrazides as versatile models

Vanadium(V) Oxoperoxo Complexes with Sid

Vanadium(V) Oxoperoxo Complexes with Side Chain SubstitutedN-Salicylidenehydrazides: Modeling Supramolecular Interactions inVanadium Haloperoxidases

✍ Simona Nica; Axel Pohlmann; Winfried Plass 📂 Article 📅 2005 🏛 John Wiley and Sons 🌐 English ⚖ 110 KB

## Abstract The Schiff‐base ligand derived from salicylaldehyde and γ‐hydroxybutanoic acid hydrazide (H~2~Salhyhb) reacts with potassium metavanadate and hydrogen peroxide in a water/methanol solution with a pH value of around two to yield the corresponding vanadium(V) oxoperoxo complex [VO(O~2~)HS